VINYLTHIONOPHOSPHORIC ACID ESTERS AND THEIR USE AS INSECTICIDES AND ACARICIDES
- 申请公布号：
- ZA7604988(B)
- 申请号：
- ZA19760004988
- 申请日期：
- 1976.08.19
- 申请公布日期：
- 1977.07.27
- 申请人：
- BAYER AG
- 发明人：
- BEHRENZ W;HAMMANN I;UHRHAN P;HOMEYER B;RIEBEL H;SCHROEDER R;HOFER W;MAURER F
- 分类号：
- A01N57/14;C07F9/173
- 主分类号：
- A01N57/14
- 摘要：
- 1506554 Substituted vinyl thiophosphate esters BAYER AG 19 Aug 1976 [20 Aug 1975] 34604/76 Heading C2P The invention comprises compounds of the general formula in which R, R 3 and R 4 are each C 1 -C 6 alkyl, R 1 is H or methyl, R 2 is CN, halogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 1 -C 4 alkylthio, or phenyl and n is an integer from 1 to 5. They are prepared by reacting (R<SP>3</SP>O)(R 4 O)P(S) Hal where Hal is halogen, preferably Cl, with a compound of the formula wherein M is H or an equivalent of an alkali metal, alkaline earth metal or ammonium, if appropriate in the presence of an acid acceptor. The reaction is preferably carried out in a solvent or diluent and preferably at 40 to 70‹ C. The products have insecticidal and acaricidal properties and may be used as active ingredients in conventional pesticidal compositions.
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